Flame Retardant Mechanism of Magnesium Hydroxide


 

When magnesium hydroxide is heated at 340 ℃-490 ℃, it will decompose and absorb the heat on the surface of the combustion product, thus playing the role of flame retardant. At the same time, it will release a large amount of water to dilute the oxygen on the surface of the combustion, and the active magnesium oxide generated by decomposition will adhere to the surface of the combustible, further preventing the combustion.

Secondly, magnesium hydroxide in the whole flame retardant process not only does not produce any harmful substances, and magnesium hydroxide decomposition products in the flame retardant effect at the same time, but also can absorb a large number of plastics, rubber and other polymer combustion smoke and harmful gases, active magnesium oxide can continue to absorb the incomplete combustion of the melting residue, and then make the combustion quickly stop, and eliminate the smoke and prevent droplets, is a new environmentally friendly inorganic flame retardant.

According to the chemical composition, flame retardants can be divided into two categories: organic flame retardants and inorganic flame retardants. Organic flame retardants are divided into two series of halogen and phosphorus. Because organic flame retardants have defects such as large smoke and high toxicity of decomposition products, they are gradually being replaced by inorganic flame retardants.

The main varieties of inorganic flame retardants are magnesium hydroxide, aluminum hydroxide, tin oxide, antimony oxide, molybdenum oxide, red phosphorus, zinc borate, ammonium molybdate and so on. Among them, magnesium hydroxide and aluminum hydroxide have a large amount of heat absorption due to decomposition, and the generated H2O can play a role in isolating the air, and the oxide generated after decomposition is a high-temperature resistant substance, so magnesium hydroxide and aluminum hydroxide, the two flame retardants, can not only play a role in flame retardancy, but also play a role in filling, and have the characteristics of not producing corrosive halogen and harmful gases, smokeless, non-toxic, non-dripping, non-dripping, non-volatilizing, non-volatilizing, non-volatilizing, long.

At present, the amount of aluminum hydroxide in China is more, but with the increase of polymer processing temperature, aluminum hydroxide is easy to decompose and reduce the flame retardant effect. Therefore, magnesium hydroxide gradually replaced aluminum hydroxide. Compared to aluminum hydroxide, magnesium hydroxide has the following advantages:

(I) The decomposition temperature of magnesium hydroxide is 100 ℃ higher than that of aluminum hydroxide, reaching 330 ℃, which is more helpful to improve the processing temperature of plastics, accelerate the extrusion speed and shorten the molding time;

(II) Magnesium hydroxide has high decomposition energy, which helps to absorb combustion heat and improve flame retardant efficiency;

(III) magnesium hydroxide and acid neutralization ability, can quickly neutralize the plastic in the combustion process of acid gas CO2, SO2, NOX, etc;

(IV) Magnesium hydroxide has low hardness, strong smoke suppression ability, and low friction to equipment, which is beneficial to prolong the service life of production equipment.

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What are the reasons for the failure of flame retardant after adding aluminum hydroxide flame retardant?

Everyone knows that there are two common flame retardants. Today we are going to talk about only one of them. Aluminum hydroxide flame retardant is an environmentally friendly halogen-free flame retardant, which can be widely used in fabrics, wood, plastics, and rubber., Polyurethane and other industries have ideal flame retardant effect. In the process of industrial application, it is found that flame retardant failure occurs when aluminum hydroxide flame retardant is added. The following are the reasons for the failure of aluminum hydroxide flame retardant, how to prevent it, how to deal with the operation, and restore the original function.

As a flame retardant, magnesium hydroxide also need to improve what aspects?

When it comes to flame retardants, everyone is familiar with them. Although we usually have less contact with them, we can know what they are used for from the name. Have to talk about magnesium hydroxide, we all know that its main presentation state is a granular, at present, the market sales of magnesium hydroxide particle size is larger, part of the commodity particle size up to tens of microns, immediately used as a flame retardant, poor dispersion, the physical properties of raw materials greater harm. In industrial production, physical grinding methods are generally used to reduce the particle size to 1 micron. The surface of magnesium hydroxide has high polarity and is easy to agglomerate. As the compatibility of refractory materials and polymer substrates, it not only reduces its flame retardant grade, but also causes more serious harm to the physical properties of raw materials.